Search results for "Multiple bonds"
showing 3 items of 3 documents
Theoretical search for very short metal-actinide bonds: NUIr and isoelectronic systems.
2004
, respectively. These analogues provide anexample ofthe isolobal principle, now without any outsideligands onthePt atom,asituation describedasits “autogenicisolobality”. These systems have multiple C Pt bonds. Theisolobal principle of Hoffmann refers to the similar chemicalbehaviorofansphybridandametalatomwithligands,-ML
Quantum Chemical Calculations Predict the Diphenyl Diuranium Compound [PhUUPh] To Have a Stable1Ag Ground State
2006
A very simple one-pot electrosynthesis of nitrones starting from nitro and aldehyde components
2018
The cathodic treatment of nitroarenes in the presence of aldehydes yields directly and selectively nitrones. Electrolysis can be conducted on a very simple undivided beaker-type cell under constant current conditions. The conversion tolerates multiple bonds, a variety of functional groups and heterocyclic moieties. Competing reductive conversions such as pinacolization are not observed. The green aspects of this electro-conversion are avoidance of metals, an environmentally benign solvent mixture, and stable as well as sustainable carbon electrodes.